I cannot email photos from either Iphoto or something on web to recipient.
I used to but cannot any more email photos from my Iphoto or something on a web page to a recipient.
iPhoto '11
If you are referring to iPhoto on your Mac go into iPhoto's Accounts preference pane and delete the email account there. Reboot, launch iPhoto and add it back.
If that's unsuccessful change iPhoto's email client to Mail in iPhoto's General preference pane. IMO that's a better solution as you automatically get a sent copy and have easier access to Contacts. Also if you need a template for photos Mail has some under the Stationary menu.
OT