Found a fix for "Photo Stream NOT synchronizing with Windows"
After doing so much research, and fiddling around with everything. To those people that are having issues with synchronizing Photo Stream with Windows. After downloading the iCloud, install the program, and open iCloud Control Panel. Once you open up and enable Photo Stream, this is the solution. TAKE A PICTURE OF ANYTHING. Once you do that open up the folder, and you'll notice that the pictures are starting to appear.
iPhone 5, iOS 7 Beta 5