Hi,
I took a look at
http://www.photoshoptv.com/ and was able to view episode 35 with Flash 8 (streaming), and download the .MP4 file.
First the Flash 8 issue. I have the Flash 8 plugin installed & was able to view the episode in Safari, Mozilla & Firefox. What Browser are you using? After installing Flash 8, did you restart your browser (sometimes you have to).
The .MP4 file that I downloaded uses h.264 compression for the video and AAC for the audio, so you should probably make sure you are using Quicktime 7.0 or higher to view it. (it took a while to download, btw... the file was about 100MB - so make sure you got the whole thing.)
The other option is on the Flash 8 streaming page. It says that you can use iTunes 5 or higher and subscribe to the podcast:
"If the above link doesnโt work and you already have iTunes installed you can subscribe by clicking on the advanced menu option at the top of your iTunes player and select โSubscribe to Podcastโ - in the window that appears type or paste the following address:
http://feeds.feedburner.com/photoshoptv/ - You can also subscribe by browsing to the music store and searching for โPhotoshop TVโ in the podcast directory search."
Hope this helps
---Kurt