If you're the Admin, then you should be able to use Terminal as root to log someone out like this:
sudo killall -u [username]
This should kill all processes in that user account, and it
may log them out also (I can't test this on a single user machine). If it doesn't, you can use:
sudo shutdown now
which will log out everyone and shutdown the system to single-user mode for the root/Admin user.
Hope this helps,
Mulder
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