well mac os x uses ipfw, the same thing *BSD uses, so if you just get the terminal commands for *BSS then they will work, o block an ip it would be like this
sudo ipfw add deny from xxx.xxx.xxx.xxx to any
type that into a terminal and it will block access to the ip, but i think your settings will get lost at shutdown
you also might want to search versiontracker,
Flying Buttress seems to be an application that allows for easy edition of ipfw, but i have never used it (though it seems to have a good rating on versiontracker)