Q: TV Episode on phone not syncing to iTunes library

Hi Rix133,

Thanks for the question. The following resource will help in transferring this TV episode from your iPhone to iTunes

iTunes Store: Transferring purchases from your iOS device or iPod to a computer

http://support.apple.com/kb/HT1848

Alternatively, you can access your purchase history from iTunes to download the purchase:

Downloading past purchases from the App Store, iBookstore, and iTunes Store

http://support.apple.com/kb/HT2519

And finally, you may also be interested in Automatic Downloads:

iTunes Store: How to enable Automatic Downloads

http://support.apple.com/kb/HT4539

Thanks,

Matt M.