In this case and Early 2008, 667MHz FBDIMMs have never shown to be an issue, work fine (4% hit at most, which can also be offset by using all 8 DIMM slots with four sets which improves memory bandwidth to it s best).
There have been a few 'enterprising' individuals that have had access to and used 8GB DIMMs for 32 and 64GB total memory w/o trouble but in that case you would want 800MHz DIMMs.
http://eshop.macsales.com/shop/memory/Mac-Pro-Memory#800-memory
FBDIMMs like many memory modules are not locked to a specific timing and frequency and can be backward compatible.
These from Amazon are only 2GB DIMMs but known to work in 2006-2008. When you get into 4GB the price has jumped up. And 8GB prices have been in the stratosphere, or had free access to server memory source.
2x2GB FBDIMM DDR2 667MHz @ $25
http://www.amazon.com/BUFFERED-PC2-5300-FB-DIMM-APPLE-Memory/dp/B002ORUUAC/
Komputerbay 8GB (2x 4GB) DDR2 667MHz ECC FB-DIMM (240 PIN)
http://www.amazon.com/Komputerbay-PC2-5300F-Buffered-FB-DIMM-Heatspreaders/dp/B0 05HIWD5U/
OWC 8GB FB-DIMM Memory Upgrade Kits for Apple Mac Pro 2008 Released 64GB $320
http://benchmarkreviews.com/7366/owc-8gb-fb-dimm-memory-upgrade-kits-apple-mac-p ro-2008-released/
Ideal RAM config is 8 DIMMs - offers 15% improvement memory bandwidth performance
667MHz FBDIMMs are cheap, excellent and 4% 'hit' you would never know about.
http://www.barefeats.com/harper5.html