Having looked around, I can only find two programs that support editing these "hidden" tags: Lostify and Atomic Parsley. Lostify is limited to MPEG4 video, and Atomic Parsley is limited to MPEG4 in general (.mp4, .m4a, .m4p, .m4v, .m4b). There doesn't seem to be a tool out there that lets you, say edit the iTunes Music Library.xml file, which would be dang handy.
http://home.comcast.net/~lowellstewart/lostify/
http://atomicparsley.sourceforge.net/
Has anyone come across any other options?
What I find particularly exasperating is that "rational" hand-editting of the XML file seems to have no impact (e.g., I have a bunch of podcast episodes that were downloaded individually, since they had fallen off the end of the podcast RSS... and there is no way to seamlessly merge them into a single podcast stream -- or to kick them all into the "Music" section of the library).
For that matter, short of re-encoding files, it seems that I'm stuck with Apple's decision about which of my files are audiobooks and which are music...