A system on PCIe in 1,1 as I said will not work.
Speed that YOU can see? no. benchmarks are meaningless, so even if it looks and tests "faster" for booting system, no real world improvement.
SATA II - again, is fine for the system.
Yes Apple's SATA II is pitiful and limited - not even "idenpendent" 300MB/sec PER drive bay but instead as all motherboards, they share a single controller, one which offers less than 800MB/sec total. Luckily you have two more SATA II ports.
So you won't ever get more than 275MB/sec reads from an SSD, meaning you won't see the 450MB/sec if using a SATA III 6G controller, it just does not seem to matter one iota in real world.
PCIe does matter when used for scratch or data.
I already said and pointed to Samsung 840s. And for audio, a Sonnet Tempo PRO and one or two 500-750-1000GB SSD would do very very well. Sonnet does not support their cheaper card in Mac Pro 1,1. And if 500GB is enough for your audio, then go iwth it. I don't think you need two or to do an array, you could. Or you could use a 2nd SSD for something else.
The nice thing is the Tempo allows you to have your system on one of the 4 drive bays, or one of the two ODD ports.
All hard drives in Mac Pro even thru 2012 all share SATA controller bandwidth. And all are SATA II. One reason also for separating system and data on different drives.