If you use the Show Exact Duplicates feature on a playlist you can delete all but one of the duplicates to leave one behind. The playlist stays intact but the particular songs no longer play twice or more in the list. If the play order matters then you may need to consider which duplicate you remove.
If you delete duplicates from your library, and one copy of a song was in Playlist A while a duplicate was in Playlist B then ordinarily one of the playlists will no longer contain the song. My DeDuper script fixes that as part of its functions.
On any given track you can right-click and use Show in playlist to see which playlists it is in.
DeDuper can be downloaded from the link in my first post. It aims to tidy up while automatically preserving playlist membership.
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