The newer version Apple USB Superdrive does not support use with older Mac products
that have a built-in optical drive; so that avenue is not a direct method. Other brands of
relatively inexpensive DVD+CD R/W USB drives can be used with system DVDs to boot
most later Intel-based Macs using the Apple DVD system media discs.
There also has been topic discussions in various locations online about methods to
use a firmware change to newer Apple USB Superdrive, that may work with older Macs
that have built-in optical drives, those which may have failed to function.
The change to the USB external Apple superdrive may void its warranty. I noticed a repair
page at iFixit.com showing how to swap the actual drive out of the Superdrive, and in the
added comments, someone had posted a suggested (but not recommended) method of
modifying the Apple USB Superdrive's ability to work with older unsupported Macs.
https://www.ifixit.com/Device/Apple_USB_SuperDrive (4 comment/questions, not definitive)
https://www.ifixit.com/Answers/View/23023/Can+I+use+the+AirSuperDrive+as+an+Exte rnal+Drive+the+Mac+laptops
So perhaps the idea may work, or it may not. Other less costly third-party somewhat
more disposable DVD RW USB player/recorders that can work & boot Macs have
been discussed in the ASC discussions. Several brands, a few links to online sites
that had them listed. Usually for under $50.
Good luck & happy computing! 🙂