If you're having trouble syncing your Mac's calendar, do you have Mavericks installed on your Mac? If so, what version? The early releases of Mavericks removed the ability to sync contacts and calendar from the Mac to the iOS device through iTunes -- forcing users to keep this information in iCloud or some other web-based facility. There was quite an uproar over this from privacy-sensitive individuals who didn't want their stuff in the cloud, and eventually I think this ability was restored in version 10.9.3 of Mavericks.
So if you're using Mavericks, maybe update to the latest (10.9.4) if you're still on an early version.
As for your Gmail syncing, I don't think the "Shared Calendar Alerts" has anything to do with syncing -- that feature is for when you're added to someone else's calendar event and you want to have the same alert that they get as the appointment initiator. At least, that's what I think it is for. For you to not sync to a particular Gmail account, you need to turn off the Calendar option for that account, which as you discovered only gives you the option to delete events linked to that account, or cancel.
If you have more than one Gmail account, the other account's settings should allow you to turn on Calendar syncing (if you want). You can also set that account to be the default account to sync with. But if your goal is to only sync with your Mac, check your OS version and turn off all Calendar syncing to email accounts.