I like assigning as much as I can to the 5ghz as possible because the 2.4 spectrum is so crowded with other things like cordless telephones and your neighbors Wi-Fi. 2.4 will broadcast further then 5, but something like your Apple TV is perfect for it. It will give you (or should give you) uninterrupted streaming for your ATV without any external interference. I have two Apple TV's, a Tivo ,and my iPad all on 5ghz, since they are all used for audio or video content consumption. Your iPhone's and iPod can go either way depending on which version of the devices you have.
Content viewing is amazing when your able to isolate as much as you can from everything else around you.