Confirming that your file is interlaced simply takes manual inspection provided that you are viewing the file in an application that allows you to see both fields (I usually use QuickTime Player 7 with the window at 100%).
In areas of motion, the combing of the picture due to interlaced fields should be obvious.
As for verifying that the fields are displaying in the correct order (upper field first), you will need to use something like After Effects to advance through the footage one field at a time (inspecting the footage as you go to make sure that the fields are in the correct temporal order). That, or play the footage out to a HDTV at 1080i50. If there is no jitter, then your fields are in the correct scan order.
So, you're going from ProRes to XDCAM, not the other way around? (Just curious.)
If for for some reason you are not trusting the results you are getting with the XDCAM Transfer plug-in, Adobe Media Encoder has presets for OP1a.
-Warren