Hello,
This has NOTHING to do with your MAC, it is a Samsung drive problem with the 3d NAND chips in the newer drives.
I too have the same problem, where my Samsung drives will get 500MB/s reads and write when attached to a single SATA port, but if I put 2 drives in RAID0, the speeds drop to less than 200MB/s for reads and writes.
While I own several MAC's, the info I talk about came from a PC I have that had 4 x Crucial SSD's from 2012 (the M4 series SSDs). They would get around 800MB/s reads and write on a LSI 9260-8i controller on a MSI-7522 motherboard with a Xeon X5670 2.93 CPU (clocked to 4GHz). Ironically the CPU came out of a Mac Pro that died, but the CPU's were still good so I used them in 2 PC's I built. So, this is not a slow machine, and I thought I would upgrade the SSD's in RAID0 to get faster speeds. Well, I have read on other sites of people having the same problem with Samsung drives. I used 2 x 500GB EVO drives, and they do better as single drives in JBOD that is any type of array.
The answer I keep finding is the 3d NAND chips have issues when being placed under another controller, and they don;t handle it well so the speeds are drastically slowed. Funny that a MAC user is seeing the same problem that PC folks are having, which rules out the OS or configuration or the SATA controller, as all those are different and the only common factor is the Samsung EVO drives.
Good luck, but you are in the same boat and until someone makes a controller or drive fix to enable these new EVO drives to run at full speed when in an array you will have to use them as JBOD, sorry to bring the bad news. I used one to upgrade my 2008 MBP laptop, it gave it a nice boost over the spinner that was in there before.
Dave