Two different issues - Most likely connected

Mac OS X v10.6 or later: "Insecure Startup Items folder" message appears after logging in - Apple Support

The Library folder is under "Macintosh HD," unless you renamed the startup volume. The StartupItems folder is a subfolder of Library, and the problem item is a subfolder of that.

With the Power Nap feature enabled, the computer enters a so-called standby mode after it has been in sleep on battery power for more than a certain time (one hour, by default.) In that mode, the contents of memory are saved to a file, and then the power is turned off. When the computer wakes up, the contents of memory are restored from the file. As a result, waking from sleep takes longer than it otherwise would. The benefit is that sleep can be prolonged indefinitely without draining the battery or having to restart the computer.

Late-model Macs are configured to enter standby after four hours in sleep while on AC power, in order to comply with a directive of the European Union. That behavior doesn't depend on the status of Power Nap.

You have three choices. One is to do nothing. Use the machine as designed. That's what I recommend.

The second choice is to disable Power Nap in the Energy Saver pane of System Preferences. Uncheck the box marked Enable Power Nap... in each of the tabs. You won't get the wake delay anymore, but you won't get any of the features of Power Nap either. The wake delay while on AC power won't be affected.

The third choice is to increase the delay before standby mode is triggered, or to disable standby mode completely. This is an unsupported option and you're on your own as to the consequences. If you choose to go this route, proceed as below. These instructions are for advanced users only.

Back up all data before making any changes.

These instructions must be carried out as an administrator. If you have only one user account, you are the administrator.

Drag across the line below to select it, then copy it to the Clipboard by pressing the key combination command-C:

sudo pmset –a standbydelay

Don't copy the blank space at the end of the line.

Launch the Terminal application.

Paste into the Terminal window by pressing command-V. Press the space bar, then type the delay you want, in seconds. For example, if you want to change the standby delay from the default one hour to eight hours, enter 28800. Don't put commas or other punctuation marks in the number. To disable standby, enter 0 (zero.)

When the command is complete, press return. You'll be prompted for your login password. Nothing will be displayed when you type it. Type carefully and then press return. You may get a one-time warning to be careful. If you don’t have a login password, you’ll need to set one before you can run the command. After running it, quit Terminal. If you see a message that your username "is not in the sudoers file," then you're not logged in as an administrator.

To disable standby on AC power, enter this command:

sudo pmset autopoweroff 0

and to revert to the default state,

sudo pmset autopoweroff 1

When my Macbook Pro's battery has died while using it, and once plugged in and turned back on, I get the loading bars, with the faded screen. Then it takes almost a minute to use the mouse. I don't see as an issue, for me, as it only happens to me when I let the battery die. I think why nothing works, within a second, is because it's loading everything and the system is "collecting" itself.... Be careful to not let your computer die while writing files, though, because about a month ago, I did this and my startup files got corrupted....