Hi, G4-533 -
Welcome to Apple's Discussions.
Also, can I pull the Zip drive and replace it with a second hard drive?
Folk have done that, but it is not easy - the bay used by the Zip drive is too small for a normal-size hard drive. To get one to fit you'd need to do a bit of surgery on the internal frame of the G4; due care is necessary to avoid getting bits of metal in the logic board or other places where they can do harm.
Another way would be to get a pocket-size drive, like one used in a pocket-size firewire drive.
However, given the design flow of the cooling air inside the case, heat from a hard drive in that location can be of concern.
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The real solution is to just add a second drive on top of the first one in the main bay - G4s come pre-equipped for that, typically with a two-drive sled that allows stacking the drives in the rear position, and with a spare power connector adjacent to that spot as well as a spare connector on the IDE cable.
G4 (DA) models such as yours should use the Master and Slave jumper settings when you have two drives on the built-in bus.
You can view/download a how-to PDF and/or movieclip from this page -
http://docs.info.apple.com/article.html?artnum=75313
If you are missing the two-drive sled (bracket), you can get one from sites like this one -
http://www.welovemacs.com/8052322a.html
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With the addition of a PCI ATA controller card, you can have up to four drives in normal positions in the main drive bay - two in the rear on the two-drive sled, plus one in the middle and one in the front positions.
Some while back one regular posted that he'd managed to get seven hard drives into a G4 (DA) case - he also modified the cooling system to accommodate the increased heat load.