Hi,
See also AIM Screen Names using @Mac.com or @me.com IDs to end (it is in Mountain Lion's area)
The @mac.com and @me.com name should still work as AIM valid Screen Names.
It is only in iChat up to and including the base version of iChat 6 in Lion.
The Later updated version of iChat 6 should work.
It is because during Lion Apple introduced the double Login to AIM and Apple that allows the app to confirm you can login in with the Apple ID.
Basically unless the app has logged in to Apple with the ID then the AIM server cannot see it.
To certain extent this already was the case in AIM and iChat for @me.com ID once there was no MobileMe server.
All @me.com names that became linked to iCloud IDs get around that by being iCloud IDs.
So... Later versions of iChat 6, Messages 7 in Mountain Lion, Messages 8 in Mavericks and the version in Yosemite (also called version 8) all allow Logins with Apple Issued IDs to the AIM servers.
It does help that you may have "updated" the account yourself along the way - such as Linking an @mac.com to MobileMe when MobileMe came out and again for iCloud.
This may mean that actually you have an Apple ID that has @mac.com@me.com and @icloud.com emails and all those "IDs" works as login names with the same password.

7:28 pm Friday; April 10, 2015
iMac 2.5Ghz i5 2011 (Mavericks 10.9)
G4/1GhzDual MDD (Leopard 10.5.8)
MacBookPro 2Gb (Snow Leopard 10.6.8)
Mac OS X (10.6.8),
Couple of iPhones and an iPad