This is from my WININSTALL USB2.0 stick. Notice that I have a 3.6G file (the entire Windows 64-bit ISO file) on the USB.
diskutil list
/dev/disk0
#: TYPE NAME SIZE IDENTIFIER
0: GUID_partition_scheme *1.0 TB disk0
1: EFI EFI 209.7 MB disk0s1
2: Apple_HFS Macintosh HD 741.7 GB disk0s2
3: Apple_Boot Recovery HD 650.0 MB disk0s3
4: Microsoft Basic Data rMBPBCMP 258.0 GB disk0s4
/dev/disk1
#: TYPE NAME SIZE IDENTIFIER
0: FDisk_partition_scheme *16.0 GB disk1
1: DOS_FAT_32 WININSTALL 16.0 GB disk1s1
diskutil info disk1
Device Identifier: disk1
Device Node: /dev/disk1
Part of Whole: disk1
Device / Media Name: SanDisk Cruzer Glide Media
Volume Name: Not applicable (no file system)
Mounted: Not applicable (no file system)
File System: None
Content (IOContent): FDisk_partition_scheme
OS Can Be Installed: No
Media Type: Generic
Protocol: USB
SMART Status: Not Supported
Total Size: 16.0 GB (16008609792 Bytes) (exactly 31266816 512-Byte-Units)
Volume Free Space: Not applicable (no file system)
Device Block Size: 512 Bytes
Read-Only Media: No
Read-Only Volume: Not applicable (no file system)
Ejectable: Yes
Whole: Yes
Internal: No
OS 9 Drivers: No
Low Level Format: Not supported
ls -lh
total 7622128
drwxrwxrwx 1 MyName staff 8.0K Nov 18 2014 $RECYCLE.BIN
drwxrwxrwx 1 MyName staff 8.0K Sep 23 2014 $WinPEDriver$
-rwxrwxrwx 1 MyName staff 102K Nov 18 2014 AMDr290x-14.2.PNG
-rwxrwxrwx 1 MyName staff 101K Nov 18 2014 AMDr290x-14.3.PNG
-rwxrwxrwx 1 MyName staff 2.8K Sep 23 2014 AutoUnattend.xml
drwxrwxrwx 1 MyName staff 8.0K Nov 17 2014 BootCamp
-rwxrwxrwx@ 1 MyName staff 370K Nov 18 2014 DeviceManager-1.PNG
-rwxrwxrwx 1 MyName staff 387K Nov 18 2014 DeviceManager-2.PNG
drwxrwxrwx 1 MyName staff 8.0K Nov 18 2014 System Volume Information
-rwxrwxrwx 1 MyName staff 3.6G Jul 26 2014 Windows8.1-64bit.cdr
-rwxrwxrwx 1 MyName staff 128B Aug 22 2013 autorun.inf
drwxrwxrwx 1 MyName staff 8.0K Aug 22 2013 boot
-rwxrwxrwx 1 MyName staff 418K Aug 22 2013 bootmgr
-rwxrwxrwx 1 MyName staff 1.5M Aug 22 2013 bootmgr.efi
drwxrwxrwx 1 MyName staff 8.0K Aug 22 2013 efi
-rwxrwxrwx@ 1 MyName staff 6.9K Nov 18 2014 imac5k-diskutil.rtf
-rwxrwxrwx 1 MyName staff 76K Aug 22 2013 setup.exe
drwxrwxrwx 1 MyName staff 16K Aug 22 2013 sources
drwxrwxrwx 1 MyName staff 8.0K Aug 22 2013 support