that's an iffy question. Thunderbolt 2 will only be found on the latest Mac Pro (2013). so....maybe...PCI-E expansion chassis for Mac Pro with Thunderbolt 2 interface. Cubix may make something like that, but it doesn't seem to be thunderbolt 2, instead relying on a host card. You might try SonnetTech or Magma
but these all are not cheap. OWC? not yet. the standard has just been announced,,,
where was I ? trying to answer your question. and I have to agree with IIIaass' answer: no
this article explains how it's set up and references an Apple KB article
http://www.tekrevue.com/tip/mac-pro-thunderbolt-performance/
JB