The UUIDs are not vulnerable. They are regenerated every time CS volumes and disks are erased, formatted or disks are added or removed from CS volumes.
On Macs prior to Late 2013 (which are preUEFI), the BC Assistant method of Windows installation uses the legacy BIOS method which has two limitations.
1. It needs a Hybrid MBR which cannot cross the 2TB boundary, and,
2. There is a limit for 4 entries in such MBRs.
A 3TB Fusion drive is split into three chunks on the HDD.
OSX (Part 1 < 2TB) + Windows
OSX (Part 2 > 2TB up to 3 TB)
If Windows is removed, the two OSX parts are supposed to be merged together when the Restore method is used in BCA. In your case, after Windows was removed, the merge part seems to have failed.
OSX (Part 1 = 2TB)
OSX (Part 2 > 2TB up to 3 TB)
This is not necessarily an issue. If you install Windows again, it should re-use and recreate
OSX (Part 1 < 2TB) + Windows
If you do not want/need to re-install Windows and address it, there are two options.
Option 1. Backup, Erase and Restore.
1. Back up OSX using Time Machine - Mac Basics: Time Machine backs up your Mac - Apple Support.
2. Boot into Internet Recovery - OS X: About OS X Recovery - Apple Support.
3. Erase your internal drive and restore from the TM backup in Step 1 - OS X Yosemite: Recover your entire system.
Please be aware that TM does not backup Bootcamp partitions.
Option 2. If the total storage used on the OSX side inside the CS volume is less than the size of the SSD, then
1. Remove the HDD from the CS volume, erase and initialize it and add it back again. This requires diskutil cs commands to be executed in Terminal.
2. Create a backup to ensure future restores bring back the modified layout not the current one.