No, you will have to go via your computer, or manually download them from the internet on each device - only ibooks will show in the cloud on your other devices.
You should be able to copy epubs and/or PDFs from a device's iBooks app to your computer's iTunes library via File > Devices > Transfer Purchases - that should work even though they aren't iBookstore purchases : About iBooks - Apple Support
Add ePub or PDF files that you download from other websites to your iTunes library on your computer from your iOS device
- Open iTunes.
- Connect your iOS device.
- From the menu bar, click File > Devices > Transfer Purchases.
Please note, these ePub and PDF files will only transfer once. After that, you must download them directly from the website to your computer.
If using an up-to-date Mac then do File > Move Books From iTunes in its iBooks app.
You can then sync them from iTunes to your other devices.