If you didn't have any photos in your library just launch Photos with the Option key held down and create a new library and start over with a new library in your Pictures folder.
WARNING: a Photos library can't be run from a NAS server. The format and file permissions for an NAS server is not compatible with the complex file and hard link ecosystem of a Photos or iPhoto library. A Photos library must be located on a volume that is formatted OS X Extended (journaled) with Ownership set to be ignored and connected directly to the Mac via USB, Firewire or Thunderbolt cable.
