Hi kots alk,
Thank you for contributing to the Apple Support Communities.
If I understand right, you can't transfer apps from your iPhone 6s to the latest version of iTunes using the "Transfer Purchases" option. It sounds like you've used this feature in the past, and I know it can be frustrating when features don't work as expected.
You can transfer other types of iTunes Store content (like music or podcasts) to your computer using "Transfer Purchases," but apps no longer transfer in iOS 9 and the latest version of iTunes (12.3).
Instead of transferring apps to your computer, you might want to back up your iPhone to iCloud. See How to back up your devices using iCloud or iTunes. (You can still back up with iTunes, too. It's always a good idea to keep multiple backups.)
To keep apps on your computer, download them to your iTunes library by finding them in the App Store and clicking the "Get" button. After this, you'll be able to manage them in iTunes and sync them to your iPhone if needed. For help with syncing see Sync your iPhone, iPad, and iPod with iTunes using USB.
Also, you can re-download past purchases on both your computer and iPhone:
On your computer
- Open iTunes.
- Go to the App Store.
- Under Quick Links, click Purchased.
On your iPhone, iPad, or iPod Touch
- Tap App Store.
- Tap Updates.
- Tap Purchased.
From About the App Store
For more information on downloading past purchases, see Redownload or transfer your iTunes Store purchases from an iPhone, iPad or iPod to a computer.
All the best.