I found this information at
http://pinouts.ru/Devices/ipod_pinout.shtml
I hope this helps.
Pin Signal Description
1 GND Ground ➖, internaly connected with Pin 2 on iPod motherboard
2 GND Audio & Video ground ➖, internaly connected with Pin 2 on iPod motherboard
3 Right Line Out - R ➕ (Audio output, right channel)
4 Left Line Out - L(+) (Audio output, left channel)
5 Right In Line In - R ➕
6 Left In Line In - L ➕
8 Video Out Composite video output (only when slideshow active on iPod Photo)
9 S-Video Chrominance output for iPod Color, Photo only
10 S-Video Luminance output for iPod Color, Photo only
11 GND Serial GND
12 Tx ipod sending line, Serial TxD
13 Rx ipod receiving line, Serial RxD
15 GND Ground ➖, internaly connected with pin 16 on iPod motherboard
16 GND USB GND ➖, internaly connected with pin 15 on iPod motherboard
18 3.3V 3.3V Power ➕
Stepped up to provide +5 VDC to USB on iPod Camera Connector. If iPod is put to sleep while Camera Connector is present, +5 VDC at this pin slowly drains back to 0 VDC.
19,20 +12V Firewire Power 12 VDC ➕
21 Accessory Indicator/Serial enable Different resistances indicate accessory type:
1kOhm - iPod docking station, beeps when connected
10kOhm - Takes some iPods into photo import mode
500kOhm - related to serial communication / used to enable serial communications Used in Dension Ice Link Plus car interface
1MOhm - Belkin auto adaptor, iPod shuts down automatically when power disconnected Connecting pin 21 to ground with a 1MOhm resistor does stop the ipod when power (i.e. Firewire-12V) is cut. Looks to be that when this pin is grounded it closes a switch so that on loss of power the Ipod shuts off. Dock has the same Resister.
22 TPA ➖ FireWire Data TPA ➖
23 5 VDC ➕ USB Power 5 VDC ➕
24 TPA ➕ FireWire Data TPA ➕
25 Data ➖ USB Data ➖
26 TPB ➖ FireWire Data TPB ➖
27 Data ➕ USB Data ➕
Pins 25 and 27 may be used in different manner. To force the iPod 5G to charge in any case, when 'USB Power 5 VDC' (pin 23) is fed, 25 must be connected to 5V through a 10kOhm resistor, and 27 must be connected to the Ground (for example: pin 1) with a 10kOhm resistor.
28 TPB ➕ FireWire Data TPB ➕
29,30 GND FireWire Ground ➖