Unlinking iTunes and Photos
How do I stop Photos from starting when I plug in my iPod 6th gen.?
Yosemite 10.10.5
iTunes 12.3.2.35
Mac mini, Mac OS X (10.6.8)
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When you plug your iPod into your computer and Photos opens, look on Photos' Import tab.
Uncheck the box toward the top left that says "Open Photos for this device."