You will need to restart your Mac(s), perhaps a few times, before they will update with the new wireless settings that you have saved on the AirPort Express.
Then, when you click the WiFi icon for available networks on a Mac, you will see your "old" network name, which is now only 2.4 GHz. You will also see your network name with 5 GHz added on the end....which is now only the 5 GHz network.
You will need to choose which network you want your Mac to connect to. Same for other devices.
Things are much simpler if you can use Apple's default settings......in which both 2.4 GHz and 5 GHz use the same wireless network name. If your wireless devices are working correctly, they will automatically choose either 2.4 GHz or 5 GHz based on their capabilities and distance in relation to the AirPort Express.
For example, my Mac will automatically connect to 5 GHz if it is in the same room or close proximity to the AirPort router. When the Mac is a few rooms away, it automatically connects to the 2.4 GHz signal.....since 2.4 GHz signals are significantly stronger than 5 GHz signals. Same for the iPad, iPhones, etc.
If you have an older device that can only connect to 2.4 GHz, then that device will always connect at 2.4 GHz....since it has no choice otherwise.
Unfortunately, some wireless devices are not able to automatically and correctly choose between 2.4 GHz and 5 GHz, so they get confused when they see a network that is broadcasting both 2.4 GHz and 5 GHz signals with the same name.
Printers in particular are notorious for this. The printer manufacturers in general are at least 5 years behind with their wireless technology.
So, when a printer is having trouble trying to connect to a network with both 2.4 GHz and 5 GHz signals using the same name, it sometimes helps to split the two bands up and assign different names to each band. Then, you can manually "point" the device at either the 2.4 GHz or 5 GHz network.
Later on, if you want, I'll show you how to have your Mac automatically connect to the 2.4 GHz network or the 5 GHz network when it starts up.
Did the printer connect to the 2.4 GHz network correctly? If not, then might want to go back to the default settings to keep things simple.