On the iMac.......
Open AirPort Utility (Finder > Applications > Utilities > AirPort Utility)
Click on the picture of the AirPort Express
Click Edit in the smaller window that appears
Click the Network tab at the top of the next window
Change the setting for Router Mode to read DHCP and NAT
Click Update at the lower right of the window and allow a full minute for the AirPort to restart
Power off both the "main" router and the AirPort Express
Wait a minute
Power up the main router and let it run a full minute
Then, power up the AirPort Express
The indicator light on the AirPort Express will be blinking amber slowly, but do not worry about this at this time
Check the AirPort Express and other network to verify that devices on one network cannot "see" devices on the other network
Keep an eye on things for a few hours. If all seems, to be well, you can tell the AirPort Express to ignore the Double NAT error that it is complaining about, so that it will display a green light
Double NAT can cause slow growing, no browsing, difficult connecting from a remote location and other things,but you might be able to get away with the Double NAT on a simple network. Try it and see how it works for you.