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Mar 11, 2016 4:33 AM in response to vaibhav.chaudhariby Ingo2711,No, the article Make calls using Voice over LTE (VoLTE) - Apple Support mentions, that VoLTE calls can only be made by an iPhone 6 or later model.
You can make wideband, high-quality phone calls with VoLTE on your iPhone 6 or later. To make these calls, both phones need to work with VoLTE.