I'm not sure I understand.
The synced photos wouldn't be deleted from iCloud Photo Library because they were never in iCloud Photo Library -- unless you placed them there in some other way before you turned on iCloud Photo Library on your iPad.
If you have iTunes synced photos on your iPad they will be deleted from your iPad if you turn on iCloud Photo Library on the iPad -- they won't be anywhere on your iPad or in iCloud Photo Library.
They will still be on your Mac. You can use the steps in "OS X Mavericks or earlier and Windows" in my earlier reply to upload them from your Mac directly to iCloud Photo Library and they will then automatically sync back to your iPad.
To summarize:
1) Turn on iCloud Photo Library on the iPad -- that will delete the iTunes synced photos and will upload a copy of all other photos to iCloud.
2) Manually upload the iTunes synced photos (and any others you want to) from your Mac to iCloud and they will sync back to your iPad.
Nothing will have changed on your Mac and all of the photos that you previously had on the iPad will now be on the iPad.