Hello JCH16,
Thanks for using Apple Support Communities.
If photos you're sharing from the Photos app on your iPhone aren't being shared to Facebook, then a first step I suggest is to make sure your Facebook account is set up in Settings > Facebook:
Here's how you sign in to a social-media account from the Settings menu of your iPhone, iPad, or iPod touch:
- Tap Settings, then scroll down and tap a social network, like Twitter.
- Sign in with your username and password for that social-network account. If you forget your username or password, visit the company's help page. For example, Facebook and Twitter offer online support to help you with your account.
Sign in to social networks like Facebook and Twitter on your iPhone, iPad, and iPod touch
If you're already signed in, then you can try deleting the account and then add it back.
Take care.