Messages to aliases are going to main iCloud address
I had a working @mac.com email address as of July 9, 2008 and moved to iCloud before August 1, 2012. My Apple ID and primary email address is my @mac.com address.
On September 28 all new messages sent to my aliases now appear in my primary email inbox rather than the alias inbox's. This condition is the same in all email clients including 3rd party Apps, not just Apple Mail Apps on my iMac and iOS devices and the iCloud web mail browser.