http://www.apple.com/legal/internet-services/itunes/us/terms.html#SERVICE - "Our Services are available for your use in your country of residence (“Home Country”)."... " Any other use of the Services and Content is a material breach of this Agreement. Apple may monitor your use of the Services and Content to ensure that you are following these Usage Rules."
The old wording was clearer: "The iTunes Service is available to you only in the United States, its territories, and possessions. You agree not to use or attempt to use the iTunes Service from outside these locations. Apple may use technologies to verify your compliance." - http://www.apple.com/legal/itunes/us/terms.html#SERVICE
I wonder if "technologies" means they are picking up on you being in Brazil and blocking access.