It is not advisable to spray anything into the port, as it could get into the inside of the phone. The pressure could also force and non-soluble dirt further in. See IdrisSeabright's advice on cleaning the port. The contacts are gold plated, and should not need any cleaning.
DeOxit
2 replies
Here are Apple's recommendations for cleaning your Apple product:
How to clean your Apple products - Apple Support
If you think that there's something stuck in the port, use a magnifier and a bright light. Use a non-conductive tool such as the stick from a cotton swap to carefully remove what you find.
Anyone with experience using DeOxit to clean iPhone charger port?