Yes. Green messages are SMS, Blue messages are iMessage.
iMessages can only be sent when both parties have an Apple Device, have enabled iMessage, and have internet access. If either party loses internet access, then the Messages App will default to text messages (carrier based SMS) to try send the message.
Your recipient may be in an area without internet access, either cellular or wifi, but can still recieve SMS messages through their carrier.
Read here for more: