That's odd : I checked using Sierra 10.12.6 here before suggesting duplicate/trash etc
Copy main.cf to the Desktop or some other folder, you may be able to read it then, to at least see what mail_owner is set to.
cat /etc/postfix/main.cf | grep mail_owner should work too, of course, but seeing as things seem off...
ls -leO /etc/postfix/ looks like below here : being a fresh install of Sierra in February 2017, & then usual updates. I see that a recent Sierra 10.12.6 installer has slightly later dates ( October 14 2016) but yours clearly seem off, as if some install or other incident changed them, (along with who knows what else…) even if only invalid timestamps.
total 224
-rw-r--r-- 1 root wheel compressed 11942 Sep 23 2016 LICENSE
-rw-r--r-- 1 root wheel compressed 1629 Sep 23 2016 TLS_LICENSE
-rw-r--r-- 1 root wheel compressed 21519 Sep 23 2016 access
-rw-r--r-- 1 root wheel compressed 10086 Sep 23 2016 aliases
-rw-r--r-- 1 root wheel compressed 3547 Sep 23 2016 bounce.cf.default
-rw-r--r-- 1 root wheel compressed 11796 Sep 23 2016 canonical
-rw-r--r-- 1 root wheel compressed 44 Sep 23 2016 custom_header_checks
-rw-r--r-- 1 root wheel compressed 10017 Sep 23 2016 generic
-rw-r--r-- 1 root wheel compressed 22845 Sep 23 2016 header_checks
-rw-r--r-- 1 andy wheel compressed 27308 Sep 23 2016 main.cf
-rw-r--r-- 1 root wheel compressed 27308 Sep 23 2016 main.cf.default
-rw-r--r-- 1 root wheel compressed 26863 Sep 23 2016 main.cf.proto
-rw-r--r-- 1 root wheel compressed 4736 Sep 23 2016 makedefs.out
-rw-r--r-- 1 root wheel compressed 7443 Sep 23 2016 master.cf
-rw-r--r-- 1 root wheel compressed 7443 Sep 23 2016 master.cf.default
-rw-r--r-- 1 root wheel compressed 6200 Sep 23 2016 master.cf.proto
-rw-r--r-- 1 root wheel compressed 20330 Sep 23 2016 postfix-files
drwxr-xr-x 2 root wheel - 68 Sep 23 2016 postfix-files.d
-rw-r--r-- 1 root wheel compressed 6929 Sep 23 2016 relocated
-rw-r--r-- 1 root wheel compressed 12666 Sep 23 2016 transport
-rw-r--r-- 1 root wheel compressed 12619 Sep 23 2016 virtual