Just a word of caution on your choice of SSD. It seems that
installing a Samsung EVO series (or Pro for that matter) has
had mixed success in Macs. Many install and function without
issue but there are also many that have had serious issues.
With the difficulty of replacing a drive in an iMac, not something I
would want to risk.
A very safe alternative would be to get a Thunderbolt enclosure or
a USB 3 enclosure and put the SSD in it, clone your system, and
then boot from it.
The Thunderbolt option will achieve speeds nearly as fast as mounting
internally. It is however a bit on the pricey side.
The USB3 option while not as fast as the Thunderbolt, will still be much,
much faster than the internal HDD drive. There are also completely
integrated SSD solutions for USB 3, however, I personally prefer to use
an empty enclosure and install my own drive. That way I know exactly
what is in it.
OWC has many high quality enclosures for both USB3 and Thunderbolt
and you can "roll your own" or get them with drives pre-installed.
Mac External and Internal Drives, SSD, Drive Enclosures & More!
The one big advantage of this approach, is that you do not need to
"crack open the case" and take the chance of damaging anything.
FWIW, I have been doing this from day one with my late 2013 27"
iMac and I use the internal drive as my cloned backup.