(I would just download same pics from camera twice). I now have High Sierra and want to backup my Photos Library on an external drive.
You can still do that - just double click on the library you want to use to open it - but be aware that is easy to get confused and mess things up by using the last used library instead of the library you want to use
Can I just install Photos app on an external drive to use as backup t
No - the Photos application must always be in the applications folder and there is no need to ever back it up as it is part of the OS and trivial to recover by reinstalling the OS
Can Time Machine be set to backup just one app (Photos)?
it could but that again would be pointless as the App is unimportant - the Photos library is critical that is where you photos and all other data are stored
I used it years ago and remember it backed up EVERYTHING that was done on the computer,
By default Time Machine does backup your entire computer - and if you are not backing everything up then you are 100% guaranteed to lose things sooner or later - computers, disks, people and software all fail and if you choose not to have complete current backups then you lose thing software they to - by default (and the very best plan) Time Machine does hourly backups so when thing fail you lose at the most a hour's work
If you choose to lose other data you can backup only your Photos library by dragging it to a properly formatted drive (Where is it safe to store a Photos Library? Requirements for the external drive) or by using Time Machine excluding everything except the Photos library or using other software like SuperDuper, carbon Copy Cloner or others
LN