It’s a Siri learning thing. The alarm/timer means iOS/Siri thinks this is an app you use regularly at a particular time of day. So, it sticks the icon of that app on the Dock around the time of day you use it. All in the idea this makes it easier to access. I had it doing that for the local newspaper and couldn’t figure out how to get rid of. It certainly wasn’t ”easier” to get at when the normal app icon for the newspaper was literally right above the Dock.
Took a fair amount of searching around the web to find the correct answer.
How to stop it. First, be on the iOS desktop. Swipe right to the widgets. Scroll the screen up if necesarry to see the Edit button and tap that. Tap the red minus button next to Siri so it stops trying to be so “helpful”. The timer induced icons should disappear.