I would be careful using that app if it automatically deleted the duplicate photos from the library. That's a recipe for disaster. I've not been able to test it as it doesn't have a demo version to try.
If I were you I'd create a test library and import a number of duplicated photos into it. Then run DPFP on it and verify that it is safe to use. Some duplicate finding apps just move the dups to the Trash bin without modifying the library's database. This is what kills libraries.
Those are the apps that I've been able to test:
These applications will identify and assist you in removing duplicate photos from a Photos Library:
PowerPhotos is the iPhoto Library Manager version for Photos and is very powerful. Although more expensive I would recommend it as it has more capabilities than the others like the capability to merge Photos libraries or copy photos along with their metadata between libraries.
PhotoSweeper compares bitmaps and/or histograms so it can detect duplicate images even if they have different sizes, file names, sizes and capture dates.