In Photos 3.0 you can change the color of the background of a page like described here:
Arrange photos on a book page in Photos on Mac - Apple Support
- Click a book under Projects in the sidebar.
- Double-click the page you want to change.
- Click the Options button below the page you want to change.
- Scroll through the available page layouts, then click the page layout you want.
- The book theme you use determines the available page layouts.
- To change the background color, click a color in the color bar.

It will depend on the theme of the book you picked, if black is available as a background.
Once your book is ready, you can save it as a PDF file. Then upload the PDF to a third-party prinin service. For example, Presto Photos can print Apple Books from the PDF you saved, see:
Photo Book Printing, Color Book Printing, and Calendar Printing - PrestoPhoto
To create the PDF file, see:
:
Preview a print project in Photos or iPhoto to avoid issues - Apple Support