The TV should work, but I suspect without a dedicated input for computer systems, you'll be stuck with a relatively narrow range of basic resolution settings because the mini won't be able to tell what the display is, and would default to a narrow sub-set of options the TV would otherwise be capable of displaying.
Now you have the system working with the standard display, try rebooting with the TV connected. You should see something like a 640x480 or 800x600 resolution after logging in, though if the system reverts to a distorted image, you may need to refer back to the last message and boot into safe mode and remove the windowserver files as suggested.
Once the system is running and you have a stable display, open the Displays preference pane and look to see what resolutions are listed. If there are a number, be careful to ensure you select only those that fit the correct type (ie, NTSC in North America, PAL for the UK etc). Likely you'll find that much above 800x600 the screen will look pretty fuzzy, particularly on text. This isn't true of all TVs, but generally the ones that work well at higher resolutions are those which are designed for use with computers and which carry dedicated inputs for that purpose.
You can also try experimenting with one or other of the utilities which are intended to allow wider display settings options (SwitchResX
http://www.madrau.com/ or DisplayConfigX
http://www.3dexpress.de/ ) but neither are all that easy to use.
In the event that you hit a setting that causes the system to fail to output a usable display, rebooting into safe mode and resetting the display resolution there or removing the windowserver files if that doesn't work should get you back to an operable system and allow you to keep experimenting.