You can boot an Intel Mac from a USB drive. I'm not sure what your problem stems from although it could be because one of the drives you are using is an external drive. I believe (not sure) that you would need to use two internal or two external drives in the RAID.
In your situation, however, I would not recommend using a RAID. A far better solution is to use your external drive as a simple backup drive. Use backup software to maintain your external clone with regular scheduled backups.
There is really no reason to use a RAID for your purposes. Mirrored RAIDs are used for data redundancy not backups and certainly not boot volumes. Furthermore, the RAID will be slower than your internal drive alone and slower than the slowest drive in the set - the external drive.
I have two MBPs and a MB. I have three external drives. Each drive starts with a clone of the current working system on each laptop. I use a backup program to run regular updates of the clone. Here are some backup programs I can recommend:
You can make a bootable clone using the Restore option of Disk Utility. You can also make and maintain clones with good backup software. My personal recommendations are (order is not significant):
1.
Retrospect Desktop (Commercial - not yet universal binary)
2.
Synchronize! Pro X (Commercial)
3.
Synk (Backup, Standard, or Pro)
4.
Deja Vu (Shareware)
5.
PsynchX 2.1.1 and
RsyncX 2.1 (Freeware)
6.
Carbon Copy Cloner (Freeware - 3.0 is a Universal Binary)
7.
SuperDuper! (Commercial)
Visit
The XLab FAQs and read the FAQs on maintenance, optimization, virus protection, and backup and restore. Also read
How to Back Up and Restore Your Files.
This would be my recommendation.
As for drive permissions they are set for the drive not the contents. You select the drive then press COMMAND-I to open the Get Info window. Set permissions if needed in the Ownership and Permissions section of the Get Info window.