There are two possible options: turning off color printing in the printer, or modifying all of the workstations. I do not know whether the first can be set from the printer's control or utility interface (probably a web page), but why buy a color printer if you want to turn color off? Whether you change the PPD or the presets, that has to be done to each workstation. If you change the PPD, users changing the preset will still be possible.
I am not certain why this is an issue. Most color lasers print the black and white portions of a page using only black toner, and to do a small amount of color printing is not that much more expensive. It can be more expensive to print things in grayscale, only to find that the result is unusable.