Thanks for the info guys, I left my mac off overnight and have just booted it up, here's what happened.
The mac started up as normal, found my wireless network, the date and time were OK (on some start-ups it cant find my network and I have to log-on, also the date sets at 1970), I opened my email account, checked my emails then it shut down, running for a total of 4 minutes.
I opened the mac CPU and it was not hot, during the start-up the PSU fans were working (I cleaned them a few days ago) as were the CPU fans (which is a replacement 1.47mhz from OWC). The small red light was on the logic board when I booted up.
Several days ago I booted from a system disk and managed to run disk utility, no problems were found on either of the hard disks, the machine also shutdown during this procedure.
I am using a Samsung 22 inch monitor, and have booted without the video card with the same results.
I have removed the RAM and booted with a basic 128mb with the same results.
I ran Tech Tool 4 a week or so ago, when the machine would stay on for an hour or two before crashing, and no errors were logged.
I am not sure what to do next, any advice would be greatfuly received.
Thanks
Anthony