No problem - hope it helps.
Adam Wilt has a good intro to color sampling here:
http://www.adamwilt.com/DV-FAQ-tech.html#colorSampling
And some pictures here:
http://www.adamwilt.com/pix-sampling.html
Basically it refers to one method digital video codecs reduce the amount of video data. For every four pixels across, the codec will store the luma value of each pixel (essentiall how dark/light it is), but will average the amount of chroma information for Cr and Cb (very generally red and blue) and only use one value for all four pixels for each of these.
In DV, where you've got a lot of blue or red information, this can show up jagged or blocky. If the source was DV, setting the sequence to uncompressed and applying the Color Smoothing 4:1:1 filter (in the Keying filters section of FCP) to the DV source can help.
In this case, since your material didn't originate as DV, just changing the sequence settings should do the trick.
Joe