Well I found something useful after all. The Disk Utility has an "Info" button in the top right. I might expect this to provide the same information as "diskutil info -all" you recommended, however it gives more, including the device path I was seeking. This theoretically should let me map the software devices to physical devices by examining the last bridge in the path. Here are the 8 paths for my two enclosures. The longer paths represent the daisy-chained enclosure presumably. Each NVMe M.2 device is on a different PCI bridge, so each one can run at full speed by themselves (but otherwise share the bus of course when multiple devices are accessed simultaneously).
Device tree path : IODeviceTree:/PCI0@0/PEG1@1,1/UPSB@0/DSB1@1/UPS0@0/pci-bridge@4/pci-bridge@0/pci-bridge@1/pci-bridge@0/pci-bridge@2/pci144d,a808@0/IONVMeController
Device tree path : IODeviceTree:/PCI0@0/PEG1@1,1/UPSB@0/DSB1@1/UPS0@0/pci-bridge@4/pci-bridge@0/pci-bridge@1/pci-bridge@0/pci-bridge@4/pci144d,a808@0/IONVMeController
Device tree path : IODeviceTree:/PCI0@0/PEG1@1,1/UPSB@0/DSB1@1/UPS0@0/pci-bridge@4/pci-bridge@0/pci-bridge@1/pci-bridge@0/pci-bridge@3/pci144d,a808@0/IONVMeController
Device tree path : IODeviceTree:/PCI0@0/PEG1@1,1/UPSB@0/DSB1@1/UPS0@0/pci-bridge@4/pci-bridge@0/pci-bridge@1/pci-bridge@0/pci-bridge@1/pci144d,a808@0/IONVMeController
Device tree path : IODeviceTree:/PCI0@0/PEG1@1,1/UPSB@0/DSB1@1/UPS0@0/pci-bridge@4/pci-bridge@0/pci-bridge@4/pci-bridge@0/pci-bridge@1/pci-bridge@0/pci-bridge@1/pci144d,a808@0/IONVMeController
Device tree path : IODeviceTree:/PCI0@0/PEG1@1,1/UPSB@0/DSB1@1/UPS0@0/pci-bridge@4/pci-bridge@0/pci-bridge@4/pci-bridge@0/pci-bridge@1/pci-bridge@0/pci-bridge@2/pci144d,a808@0/IONVMeController
Device tree path : IODeviceTree:/PCI0@0/PEG1@1,1/UPSB@0/DSB1@1/UPS0@0/pci-bridge@4/pci-bridge@0/pci-bridge@4/pci-bridge@0/pci-bridge@1/pci-bridge@0/pci-bridge@4/pci144d,a808@0/IONVMeController
Device tree path : IODeviceTree:/PCI0@0/PEG1@1,1/UPSB@0/DSB1@1/UPS0@0/pci-bridge@4/pci-bridge@0/pci-bridge@4/pci-bridge@0/pci-bridge@1/pci-bridge@0/pci-bridge@3/pci144d,a808@0/IONVMeController