I have compared all my 4 'devices', namely, Photos/MBA, iPhone, iPad & iCloud after taking a photograph with my iPhone. The same photo automatically appeared on all 4. Using another new photo taken using my iPhone (which as above appeared automatically on all 4 devices), I then deleted the same photo on my iPhone and the ONLY device it did not delete on was my MBA/Photos. I used the same method but this time deleted a photo on my iPad and the ONLY device it did not delete on was again my MBA/Photos.
Also after comparing all 4 devices, whilst all 4 have the same number of videos, my Photos/MBA has 3 less photos. Also, Photos has always had a few photos that appear out of order. I suspect that I have deleted photos in Photos/MBA and not the iPhone, and vice versa. I have about 1600 photos and 200 videos on all 4, including iCloud, so I have probably used methods to download photos over the years that may or may not have included syncing. I recall using iTunes but never liked using it. Now I go in a circle as I don't want to use this method anymore. Getting back to the screen shot I submitted, I may have answered your last question, as in why my photos are already in iCloud. iCloud & Photos are ticked in Sys Prefs. But in Preferences in Photos on my MBA, the iCloud Photos box is NOT ticked. And then this leads me to my screen shot which confused me as whilst I would say nearly all my photos/videos are in the cloud already (although sync does not seem to be in use), if I then tick the iCloud Photos box, why I am 'told' that I may not have enough space? I'm afraid of doubling up somehow or deleting by ticking the automatic upload & store box. Hope you can advise. Thanking you.