I take it you managed to create the bootable installer for El Capitan without difficulty,
and the problem is with making a bootable installer for macOS Sierra.
When Apple recertified their installers in October 2019 they made an error with the Sierra installer,
Apple have done nothing to rectify this even though they have been informed of this many, many times.
The error you see while trying to make a bootable install,
"Volumes/<MyVolume> is not a valid mount point, is down to a simple one character typo in the info.plist.
There is however a workaround.
With Install macOS Sierra.app in your Applications folder open Terminal.
Paste in this command
sudo plutil -replace CFBundleShortVersionString -string "12.6.03" /Applications/Install\ macOS\ Sierra.app/Contents/Info.plist
press return
enter your password
press return
now paste in the createinstallmedia command for Sierra where MyVolume can be replaced with the name of your USB stick
If your USB name has more than one word separated by spaces you would need to type it in as
/The\ USB\ Name
sudo /Applications/Install\ macOS\ Sierra.app/Contents/Resources/createinstallmedia --volume /Volumes/MyVolume --applicationpath /Applications/Install\ macOS\ Sierra.app
press return
follow the prompts