Catalina is max for the 2013 iMac.
macOS Catalina 10.15.7 - Technical Specifications
General Requirements
OS X 10.9 or later
4GB of memory
12.5GB of available storage (OS X El Capitan 10.11.5 or later)*
Some features require an Apple ID; terms apply.
Some features require a compatible internet service provider; fees may apply.
Mac Hardware Requirements
For details about your Mac model, click the Apple icon at the top left of your screen and choose About This Mac. These Mac models are compatible with macOS Catalina:
MacBook (Early 2015 or newer)
MacBook Air (Mid 2012 or newer)
MacBook Pro (Mid 2012 or newer)
Mac mini (Late 2012 or newer)
iMac (Late 2012 or newer)
iMac Pro (2017)
Mac Pro (Late 2013 or newer)
https://support.apple.com/en-us/HT210190
Don't use FireFox for these links…
https://apps.apple.com/gb/app/macos-catalina/id1466841314?ls=1&mt=12
How to upgrade to macOS Catalina – Apple Support
And caution on 10.15 or higher, to see which Apps will no longer work in 10.15 get Go64...
https://www.stclairsoft.com/Go64/
Next step up would've been...
macOS Big Sur - Technical Specifications
General Requirements
OS X 10.9 or later
4GB of memory
35.5GB available storage on macOS Sierra or later*
Some features require an Apple ID; terms apply.
Some features require a compatible internet service provider; fees may apply.
Mac Hardware Requirements
For details about your Mac model, click the Apple icon at the top left of your screen and choose About This Mac. These Mac models are compatible with macOS Big Sur:
MacBook (2015 or later)
MacBook Air (2013 or later)
MacBook Pro (Late 2013 or later)
Mac mini (2014 or later)
iMac (2014 or later)
iMac Pro (2017 or later)
Mac Pro (2013 or later)
Learn about compatibility and how to identify your specific Mac model
Don't use FireFox or WaterFox for this link. it'll mess it up...
https://apps.apple.com/us/app/macos-big-sur/id1526878132?ls=1&mt=12